Gravita Exim Refining Plant use pyrometallurgical process for Lead Refining, producing Lead with a minimum purity level of 99.97% from furnace tapped crude Lead. We supply refining kettle furnaces of various capacities ranging from 5-100 tonnes per batch, accompanied by high efficiency natural gas burners / furnace oil burners, equipped with preheating arrangements. Emissions are controlled by a flexible kettle hood, venting into a venturi type wet scrubber, attached to an Induced Draft Fan along with a chimney/stack arrangement.


Enclosure Hooding - Refining Kettle Emissions Control

We also provide additional equipment for automatic dross removal. On demand, we supply a range of special fluxes designed to reduce dross formation and increase process efficiency. The refining unit complement is completed by the automatic Lead ingot-casting machine (with Lead-Pump) having a production capacity of up to 25 tonnes/hr. Our refining unit package is optimally configured for high throughput with good emission control, as proven by the existing installations in operation.

Recycled Lead Processing - Refining

The removal of impurities and other metals from the crude Lead (S, Cu,Ni, As, Sb, Bi, Ag, Au, etc.). The refining process is applied in several steps in kettles with addition of specific agents alternatively smaller quantities are processed by electrolytic refining.

A smelting plant stops at the stage of the fusion-reduction plant, it will produce what is known as hard or Antimonial Lead. If the plant is meant to produce soft Lead, the crude Lead must undergo a refining process. The objective of the refining process is to remove almost all copper (Cu), antimony (Sb), arsenic (As) and tin (Sn), since soft Lead are not allowed to have more than 10g per ton of these metals.

Pyrometallurgical Refining

Pyrometallurgical Refining is performed in liquid phase, which means that the crude Lead must be melted to temperatures from 327�C (Lead fusion point) to 650�C. As a general trend, the process is performed in batches of 20 to 200 tons, according to the refining plant capacity. The chemical concept behind the refining process is the addition of specific reagents to the molten Lead at proper temperatures. These reagents will then remove the unwanted metals in a specific order as they are added selectively.

Copper (Cu) is the first element to be removed with elementary Sulphur in a two phase procedure. In the first step, almost all copper is removed as a copper sulfide (CuS) skims when elementary Sulphur is added to the molten Lead at 450�C. The second step is meant to remove all remaining copper by adding small amounts of elementary Sulphur to the molten Lead at 330�C until no reaction takes place anymore. Tin (Sn) is next removed BY either chlorine (Cl2) or ammonium chloride (NH4Cl) oxidation. The addition of chlorine to the molten Lead at 500�C produces tin chloride (SnCl2) skims which are mechanically removed. Although this is the current method for tin removal, its inconvenient is the parallel removal of small amounts of antimony (Sb) and arsenic (As) by oxidation.

Author: Gravita Exim Ltd

About the author:
The Gravita Group is owned and managed by a forward-looking team of professionals, with an experience in Battery Processing & Lead Recycling Technology of more than 15 years.

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